在密闭条件中,在一定温度下,与固体或液体处于相平衡的蒸气所具有的压强称为饱和蒸气压。同一物质在不同温度下有不同的饱和蒸气压,并随着温度的升高而增大。纯溶剂的饱和蒸气压大于溶液的饱和蒸气压;对于同一物质,固态的饱和蒸气压小于液态的饱和蒸气压。
温度 | 饱和蒸气压 |
t/℃ | (×10 3Pa) |
0 | 0.61129 |
1 | 0.65716 |
2 | 0.70605 |
3 | 0.75813 |
4 | 0.81359 |
5 | 0.8726 |
6 | 0.93537 |
7 | 1.0021 |
8 | 1.073 |
9 | 1.1482 |
10 | 1.2281 |
11 | 1.3129 |
12 | 1.4027 |
13 | 1.4979 |
14 | 1.5988 |
15 | 1.7056 |
16 | 1.8185 |
17 | 1.938 |
18 | 2.0644 |
19 | 2.1978 |
20 | 2.3388 |
21 | 2.4877 |
22 | 2.6447 |
23 | 2.8104 |
24 | 2.985 |
25 | 3.169 |
26 | 3.3629 |
27 | 3.567 |
28 | 3.7818 |
29 | 4.0078 |
30 | 4.2455 |
31 | 4.4953 |
32 | 4.7578 |
33 | 5.0335 |
34 | 5.3229 |
35 | 5.6267 |
36 | 5.9453 |
37 | 6.2795 |
38 | 6.6298 |
39 | 6.9969 |
40 | 7.3814 |
41 | 7.784 |
42 | 8.2054 |
43 | 8.6463 |
44 | 9.1075 |
45 | 9.5898 |
46 | 10.094 |
47 | 10.62 |
48 | 11.171 |
49 | 11.745 |
50 | 12.344 |
51 | 12.97 |
52 | 13.623 |
53 | 14.303 |
54 | 15.012 |
55 | 15.752 |
56 | 16.522 |
57 | 17.324 |
58 | 18.159 |
59 | 19.028 |
60 | 19.932 |
61 | 20.873 |
62 | 21.851 |
63 | 22.868 |
64 | 23.925 |
65 | 25.022 |
66 | 26.163 |
67 | 27.347 |
68 | 28.576 |
69 | 29.852 |
70 | 31.176 |
71 | 32.549 |
72 | 33.972 |
73 | 35.448 |
74 | 36.978 |
75 | 38.563 |
76 | 40.205 |
77 | 41.905 |
78 | 43.665 |
79 | 45.487 |
80 | 47.373 |
81 | 49.324 |
82 | 51.342 |
83 | 53.428 |
84 | 55.585 |
85 | 57.815 |
86 | 60.119 |
87 | 62.499 |
88 | 64.958 |
89 | 67.496 |
90 | 70.117 |
91 | 72.823 |
92 | 75.614 |
93 | 78.494 |
94 | 81.465 |
95 | 84.529 |
96 | 87.688 |
97 | 90.945 |
98 | 94.301 |
99 | 97.759 |
100 | 101.32 |
101 | 104.99 |
102 | 108.77 |
103 | 112.66 |
104 | 116.67 |
105 | 120.79 |
106 | 125.03 |
107 | 129.39 |
108 | 133.88 |
109 | 138.5 |
110 | 143.24 |
111 | 148.12 |
112 | 153.13 |
113 | 158.29 |
114 | 163.58 |
115 | 169.02 |
116 | 174.61 |
117 | 180.34 |
118 | 186.23 |
119 | 192.28 |
120 | 198.48 |
121 | 204.85 |
122 | 211.38 |
123 | 218.09 |
124 | 224.96 |
125 | 232.01 |
126 | 239.24 |
127 | 246.66 |
128 | 254.25 |
129 | 262.04 |
130 | 270.02 |
131 | 278.2 |
132 | 286.57 |
133 | 295.15 |
134 | 303.93 |
135 | 312.93 |
136 | 322.14 |
137 | 331.57 |
138 | 341.22 |
139 | 351.09 |
140 | 361.19 |
141 | 371.53 |
142 | 382.11 |
143 | 392.92 |
144 | 403.98 |
145 | 415.29 |
146 | 426.85 |
147 | 438.67 |
148 | 450.75 |
149 | 463.1 |
150 | 475.72 |
151 | 488.61 |
152 | 501.78 |
153 | 515.23 |
154 | 528.96 |
155 | 542.99 |
156 | 557.32 |
157 | 571.94 |
158 | 586.87 |
159 | 602.11 |
160 | 617.66 |
161 | 633.53 |
162 | 649.73 |
163 | 666.25 |
164 | 683.1 |
165 | 700.29 |
166 | 717.83 |
167 | 735.7 |
168 | 753.94 |
169 | 772.52 |
170 | 791.47 |
171 | 810.78 |
172 | 830.47 |
173 | 850.53 |
174 | 870.98 |
175 | 891.8 |
176 | 913.03 |
177 | 934.64 |
178 | 956.66 |
179 | 979.09 |
180 | 1001.9 |
181 | 1025.2 |
182 | 1048.9 |
183 | 1073 |
184 | 1097.5 |
185 | 1122.5 |
186 | 1147.9 |
187 | 1173.8 |
188 | 1200.1 |
189 | 1226.1 |
190 | 1254.2 |
191 | 1281.9 |
192 | 1310.1 |
193 | 1338.8 |
194 | 1368 |
195 | 1397.6 |
196 | 1427.8 |
197 | 1458.5 |
198 | 1489.7 |
199 | 1521.4 |
200 | 1553.6 |
201 | 1568.4 |
202 | 1619.7 |
203 | 1653.6 |
204 | 1688 |
205 | 1722.9 |
206 | 1758.4 |
207 | 1794.5 |
208 | 1831.1 |
209 | 1868.4 |
210 | 1906.2 |
211 | 1944.6 |
212 | 1983.6 |
213 | 2023.2 |
214 | 2063.4 |
215 | 2104.2 |
216 | 2145.7 |
217 | 2187.8 |
218 | 2230.5 |
219 | 2273.8 |
220 | 2317.8 |
221 | 2362.5 |
222 | 2407.8 |
223 | 2453.8 |
224 | 2500.5 |
225 | 2547.9 |
226 | 2595.9 |
227 | 2644.6 |
228 | 2694.1 |
229 | 2744.2 |
230 | 2795.1 |
231 | 2846.7 |
232 | 2899 |
233 | 2952.1 |
234 | 3005.9 |
235 | 3060.4 |
236 | 3115.7 |
237 | 3171.8 |
238 | 3288.6 |
239 | 3286.3 |
240 | 3344.7 |
241 | 3403.9 |
242 | 3463.9 |
243 | 3524.7 |
244 | 3586.3 |
245 | 3648.8 |
246 | 3712.1 |
247 | 3776.2 |
248 | 3841.2 |
249 | 3907 |
250 | 3973.6 |
251 | 4041.2 |
252 | 4109.6 |
253 | 4178.9 |
254 | 4249.1 |
255 | 4320.2 |
256 | 4392.2 |
257 | 4465.1 |
258 | 4539 |
259 | 4613.7 |
260 | 4689.4 |
261 | 4766.1 |
262 | 4843.7 |
263 | 4922.3 |
264 | 5001.8 |
265 | 5082.3 |
266 | 5163.8 |
267 | 5246.3 |
268 | 5329.8 |
269 | 5414.3 |
270 | 5499.9 |
271 | 5586.4 |
272 | 5674 |
273 | 5762.7 |
274 | 5852.4 |
275 | 5943.1 |
276 | 6035 |
277 | 6127.9 |
278 | 6221.9 |
279 | 6317.2 |
280 | 6413.2 |
281 | 6510.5 |
282 | 6608.9 |
283 | 6708.5 |
284 | 6809.2 |
285 | 6911.1 |
286 | 7014.1 |
287 | 7118.3 |
288 | 7223.7 |
289 | 7330.2 |
290 | 7438 |
291 | 7547 |
292 | 7657.2 |
293 | 7768.6 |
294 | 7881.3 |
295 | 7995.2 |
296 | 8110.3 |
297 | 8226.8 |
298 | 8344.5 |
299 | 8463.5 |
300 | 8583.8 |
301 | 8705.4 |
302 | 8828.3 |
303 | 8952.6 |
304 | 9078.2 |
305 | 9205.1 |
306 | 9333.4 |
307 | 9463.1 |
308 | 9594.2 |
309 | 9726.7 |
310 | 9860.5 |
311 | 9995.8 |
312 | 10133 |
313 | 10271 |
314 | 10410 |
315 | 10551 |
316 | 10694 |
317 | 10838 |
318 | 10984 |
319 | 11131 |
320 | 11279 |
321 | 11429 |
322 | 11581 |
323 | 11734 |
324 | 11889 |
325 | 12046 |
326 | 12204 |
327 | 12364 |
328 | 12525 |
329 | 12688 |
330 | 12852 |
331 | 13019 |
332 | 13187 |
333 | 13357 |
334 | 13528 |
335 | 13701 |
336 | 13876 |
337 | 14053 |
338 | 14232 |
339 | 14412 |
340 | 14594 |
341 | 14778 |
342 | 14964 |
343 | 15152 |
344 | 15342 |
345 | 15533 |
346 | 15727 |
347 | 15922 |
348 | 16120 |
349 | 16320 |
350 | 16521 |
351 | 16825 |
352 | 16932 |
353 | 17138 |
354 | 17348 |
355 | 17561 |
356 | 17775 |
357 | 17992 |
358 | 18211 |
359 | 18432 |
360 | 18655 |
361 | 18881 |
362 | 19110 |
363 | 19340 |
364 | 19574 |
365 | 19809 |
366 | 20048 |
367 | 20289 |
368 | 20533 |
369 | 20780 |
370 | 21030 |
371 | 21286 |
372 | 21539 |
373 | 21803 |